The list below includes the names of governors and administrators that has led Enugu state since the formation of the state in august 1991 following her split from Anambra state.
| NAME | PARTY | TITLE | PERIOD |
| Herbert Eze | Military | Governor | Aug 1999 – Jan. 1992 |
| Okwesilieze Nwodo | NRC | Governor | Jan. 1992 – Nov. 1993 |
| Temi Ejoor | Military | Administrator | Dec. 1993 – Sept. 1994 |
| Mike Torey | Military | Administrator | Sept. 1994 – Aug. 1996 |
| Sule Ahman | Military | Administrator | Aug. 1996 – Aug 1998 |
| Adewunmi Agbaje | Military | Administrator | Aug. 1998 – May 1999 |
| Chimaroke Nnamani | PDP | Governor | May 1999 – May 2007 |
| Sullivan Chime | PDP | Governor | May 2007 – May 2015 |
| Ifeanyi Ugwuanyi | PDP | Governor | May 2015 – date |
